• 文献标题:   Epoxy-Graphene UV-cured nanocomposites
  • 文献类型:   Article
  • 作  者:   MARTINGALLEGO M, VERDEJO R, LOPEZMANCHADO MA, SANGERMANO M
  • 作者关键词:   graphene, nanocomposite, photopolymerization
  • 出版物名称:   POLYMER
  • ISSN:   0032-3861 EI 1873-2291
  • 通讯作者地址:   Politecn Torino
  • 被引频次:   88
  • DOI:   10.1016/j.polymer.2011.08.039
  • 出版年:   2011

▎ 摘  要

This work presents the preparation of functionalized graphene sheets (FGS)/epoxy coatings cured by cationic photopolymerization with enhanced mechanical properties. The kinetics of the photopolymerization process for formulations up to 1.5 wt% of graphene were evaluated by means of Real-Time FTIR spectroscopy. The reinforcement of the cured coatings by the graphene was studied by measuring the dynamic-mechanical properties and the surface hardness. An increase of almost 40 degrees C in the T-g was obtained by adding 1.5 wt% of graphene to the epoxy matrix. A good dispersion state and interaction of the graphene with the matrix were observed by TEM and FESEM analyses. (C) 2011 Elsevier Ltd. All rights reserved.