• 文献标题:   The synergistic effect of nitrogen doping and para-phenylenediamine functionalization on the physicochemical properties of reduced graphene oxide for electric double layer supercapacitors in organic electrolytes
  • 文献类型:   Article
  • 作  者:   YANG J, SHIN J, PARK M, LEE GH, AMEDZOADORE M, KANG YM
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Dongguk Univ Seoul
  • 被引频次:   10
  • DOI:   10.1039/c7ta03194g
  • 出版年:   2017

▎ 摘  要

The presence of nitrogen atoms in reduced graphene oxide (RGO) sheets considerably modulates their intrinsic physical and chemical properties to finally improve their electrochemical properties in electric double layer supercapacitors. However, this also accelerates the restacking phenomena of RGO, which results in a decreased active surface area and pore volume. To solve this problem, we fabricated paraphenylenediamine (p-PDA) functionalized nitrogen doped RGO (NRGO) to inhibit the restacking phenomenon and thus preserve the active surface area and pore volume via chemical bonding between RGO and p-PDA. Finally, we realized an impressive electrochemical performance through the synergistic effect of nitrogen doping and p-PDA functionalization.