• 文献标题:   Polydopamine functionalized graphene/NiFe2O4 nanocomposite with improving Li storage performances
  • 文献类型:   Article
  • 作  者:   XIAO YL, ZAI JT, LI XM, GONG Y, LI B, HAN QY, QIAN XF
  • 作者关键词:   nife2o4, functionalization, anode material, graphene, polydopamine
  • 出版物名称:   NANO ENERGY
  • ISSN:   2211-2855 EI 2211-3282
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   66
  • DOI:   10.1016/j.nanoen.2014.03.006
  • 出版年:   2014

▎ 摘  要

Polydopamine (PDA) functionalized graphene/NiFe2O4 (GNSs-PDA-NiFe2O4) nanocomposite has been successfully synthesized through an in-situ ultrasonic method. The obtained GNSs-PDA-NiFe2O4 nanocomposite shows a reversible capacity up to 947 mAh g(-1) and much improved rate capability, e.g. delivering a capacity of 562 mAh g(-1) at 5 A g(-1), about 7 times higher than that of graphene/NiFe2O4 nanocomposite. The improvement in the rate capability of the obtained GNSs-PDA-NiFe2O4 nanocomposite can be attributed to the improved interactions between graphene and NiFe2O4 derived from PDA, and a high conductive network fabricated by PDA functionalized graphene, which can be supported by TEM images and EIS measurements. Further studies reveal the strong graphene-NiFe2O4 interactions are also beneficial for retaining the high conductive network after the charge-discharge processes, and further beneficial for its cyclic stability. (C) 2014 Elsevier Ltd. All rights reserved.