• 文献标题:   Microstructured nitrogen-doped graphene-Sn composites as a negative electrode for high performance lithium-ion hybrid supercapacitors
  • 文献类型:   Article
  • 作  者:   GRANADOSMORENO M, MORENOFERNANDEZ G, CID R, GOMEZURBANO JL, CARRIAZO D
  • 作者关键词:  
  • 出版物名称:   SUSTAINABLE ENERGY FUELS
  • ISSN:   2398-4902
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1039/d1se01779a EA JAN 2022
  • 出版年:   2022

▎ 摘  要

Herein, we report a simplistic single-step synthesis of nitrogen-doped graphene decorated with tin particles suitable as a negative (battery-type) electrode for lithium-ion hybrid capacitors. An activated carbon derived from a graphene-carbon composite is used as a positive (capacitor-type) electrode. The excellent features of the nitrogen-doped graphene matrix combined with the homogeneous distribution and high theoretical capacity (994 mA h g(-1)) of the submicrometer-sized tin particles lead to an improved performance of the negative electrode, especially at high current densities. An optimized dual-carbon lithium-ion capacitor with 2 : 1 positive to negative mass ratio delivers high energy and power densities (133 W h kg(-1) at 142 W kg(-1) and 51 W h kg(-1) at 25 600 W kg(-1)). Furthermore, within a discharge time of 1 min, the device reaches 19 000 cycles with full capacity retention, delivering ca. 100 W h kg(-1) at 5600 W kg(-1).