• 文献标题:   Sodium deoxycholate functionalized graphene and its composites with polyvinyl alcohol
  • 文献类型:   Article
  • 作  者:   WANG LW, LIAO RJ, TANG ZH, LEI YD, GUO BC
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICS DAPPLIED PHYSICS
  • ISSN:   0022-3727 EI 1361-6463
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   12
  • DOI:   10.1088/0022-3727/44/44/445302
  • 出版年:   2011

▎ 摘  要

Sodium deoxycholate (SDC), a kind of bile derivative, is used to noncovalently functionalize graphene. Stable and high concentration (up to 20 mg ml(-1)) of graphene colloid is obtained. The stabilization mechanism is revealed to be hydrophobic interaction, electrostatic repulsion and hydrogen bonding. Single-layer and few-layer graphene are obtained in the colloid. Subsequently, the obtained graphene sheets are incorporated into a polyvinyl alcohol (PVA) matrix by solution casting to fabricate PVA/graphene composites. Morphological observations substantiate the homogeneous dispersion of graphene in the PVA matrix and strong interfacial adhesion between them. Significant improvements in tensile strength and modulus of the composite films are observed.