• 文献标题:   Water Soluble Graphene Oxide/Poly(1-vinylimidazole) Composites: Synthesis and Characterization
  • 文献类型:   Article
  • 作  者:   LINGAPPAN N, KIM DH, PARK JM, LIM KT
  • 作者关键词:   graphene oxide, poly 1vinylimidazole, covalent functionalization, silylation, polymer nanocomposite
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Pukyong Natl Univ
  • 被引频次:   5
  • DOI:   10.1166/jnn.2014.8823
  • 出版年:   2014

▎ 摘  要

Modified graphene oxide/poly(1-vinylimidazole) (mGO/PVIm) composites were prepared via surface-initiated free radical graft polymerization. First, the hydroxyl-enriched GO sheets were functionalized with 3-methacryloxypropyltrimethoxysilane to introduce active-vinyl groups on the GO surfaces. Subsequently, 1-vinylimidazole was chemically grafted and polymerized in the presence of mGO. The chemical structures and morphology of the covalently bonded composites were characterized using FTIR, XPS, TGA, HRTEM, FESEM and XRD measurements. The mGO/PVIm composites exhibit a stable dispersion in water and show high storage stability (>10 days). Furthermore, the morphological analysis showed that mGO was homogeneously dispersed in the polymer matrix.