• 文献标题:   Nitrogen-doped graphene-supported cobalt carbonitride@oxide core-shell nanoparticles as a non-noble metal electrocatalyst for an oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   WU YS, SHI QQ, LI YH, LAI ZC, YU H, WANG HJ, PENG F
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   41
  • DOI:   10.1039/c4ta03850a
  • 出版年:   2015

▎ 摘  要

A new catalyst, cobalt carbonitride (CoCN) nanoparticles supported on nitrogen-doped graphenes (NG), was synthesized via a high temperature ammonia nitridation method. The catalyst has a core-shell structure with a highly active CoCN core and a protective cobalt oxide shell. Linear sweep voltammetry measurements show that the catalyst presents excellent activity in an oxygen reduction reaction compared to cobalt oxide supported on NG and commercial Pt/C catalysts, benefiting from the strong synergistic effect between CoCN and NG and the electronic modification of cobalt oxide by CoCN from within.