• 文献标题:   Synthesis of alpha-Fe2O3 nanoparticles from Fe(OH)(3) sol and their composite with reduced graphene oxide for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   DU M, XU CH, SUN J, GAO L
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   44
  • DOI:   10.1039/c3ta00183k
  • 出版年:   2013

▎ 摘  要

alpha-Fe2O3/reduced graphene oxide (alpha-Fe2O3/RGO) composite has been synthesized by a facile hydrothermal method. Fe(OH)(3) sol is creatively employed as the precursor and no nucleating agent is employed to help Fe3+ change to Fe(OH)(3). In the hydrothermal process, Fe(OH)(3) sol transforms to alpha-Fe2O3 particles and GO becomes RGO with hydrazine hydrate. Composites with different ratios between alpha-Fe2O3 and RGO for comparison are investigated as anode LIB materials. Among the composites, the alpha-Fe2O3/RGO containing 73% alpha-Fe2O3 exhibits the highest reversible specific capacity of similar to 950 mA h g(-1) after 70 cycles at a current density of 100 mA g(-1). When the current density is 800 mA g(-1), the capacity still remains as-700 mA h g(-1), showing superior rate capability. The significant electrochemical property improvements of alpha-Fe2O3/RGO can be attributed to the uniform alpha-Fe2O3 nanoparticles (20-30 nm) and the RGO substrate, which provides high electrical conductivity and stability.