• 文献标题:   Recognizing nitrogen dopant atoms in graphene using atomic force microscopy
  • 文献类型:   Article
  • 作  者:   VAN DER HEIJDEN NJ, SMITH D, CALOGERO G, KOSTER RS, VANMAEKELBERGH D, VAN HUIS MA, SWART I
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW B
  • ISSN:   2469-9950 EI 2469-9969
  • 通讯作者地址:   Univ Utrecht
  • 被引频次:   5
  • DOI:   10.1103/PhysRevB.93.245430
  • 出版年:   2016

▎ 摘  要

Doping graphene by heteroatoms such as nitrogen presents an attractive route to control the position of the Fermi level in the material. We prepared N-doped graphene on Cu(111) and Ir(111) surfaces via chemical vapor deposition of two different molecules. Using scanning tunneling microscopy images as a benchmark, we show that the position of the dopant atoms can be determined using atomic force microscopy. Specifically, the frequency shift-distance curves Delta f(z) acquired above a N atom are significantly different from the curves measured over a C atom. Similar behavior was found for N-doped graphene on Cu(111) and Ir(111). The results are corroborated by density functional theory calculations employing a van der Waals functional.