• 文献标题:   Cyclodextrin edge functionalized graphene oxide modified poly (phthalazinone ether ketone) composite membrane with enhanced properties for anion exchange membrane
  • 文献类型:   Article
  • 作  者:   ZHANG S, ZHU XL, JIN CH, ZHANG ZH
  • 作者关键词:   graphene oxide, poly phthalazinone ether ketone, anion exchange membrane, selfassembling, cyclodextrin
  • 出版物名称:   SOLID STATE IONICS
  • ISSN:   0167-2738 EI 1872-7689
  • 通讯作者地址:   Dalian Univ Technol
  • 被引频次:   5
  • DOI:   10.1016/j.ssi.2018.03.024
  • 出版年:   2018

▎ 摘  要

Composite membranes have shown promising advantages over alkaline doped membranes when used as fuel cells separation membrane. A series of poly(phthalazinone ether ketone) (PPEK) with different loading of quatemary ammonium groups modified cyclodextrins functional graphene oxide (QA-CD beta@GO) composite membrane were synthesized by self-assembling. The prepared composite membranes exhibited good thermal stability and enhanced mechanical properties. Meanwhile, the 10% QA-CD beta@GO/PPEK membranes exhibited an acceptable hydroxide conductivity of 42.37 mS.cm(-1) at 80 degrees C and alkaline stability for 400 h. In addition, the swelling ratio of the composite membranes was lower than 20%. Furthermore, the results revealed that graphene oxide composite membrane could be used as anion exchange membrane.