• 文献标题:   Bismuth oxyiodide incorporated reduced graphene oxide nanocomposite material as an efficient photocatalyst for visible light assisted degradation of organic pollutants
  • 文献类型:   Article
  • 作  者:   VINOTH R, BABU SG, RAMACHANDRAN R, NEPPOLIAN B
  • 作者关键词:   bioirgo, bandgap tailoring, degradation, hydroxyl radical, reusability
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   SRM Univ
  • 被引频次:   15
  • DOI:   10.1016/j.apsusc.2017.01.278
  • 出版年:   2017

▎ 摘  要

Herein, Bismuth oxyiodide (BiOI) - reduced graphene oxide (rGO) photocatalysts were prepared via simple hydrothermal method. The BiOI-rGO photocatalyst exhibited high crystallinity with tetragonal phase of BiOI. In addition, the electronic interaction between rGO sheet and BiOI reduced the band-gap value from 1.86 eV of bare BiOI to 1.51 eV of BiOI-rGO (6 wt%) photocatalyst. More interestingly, the rGO showed a strong influence on tailoring the morphology of BiOI to different nanostructures with different rGO loading (wt%), which further reflected differences in the photocatalytic activity. A significant quenching in the photoluminescence intensity of rGO supported BiOI photocatalyst confirmed the effective suppression of electron -hole pair recombination. The optimized rGO (4 wt%) loaded BiOI photocatalyst significantly improved the photocatalytic activity (similar to 85%) towards the degradation of methyl orange (MO) dye compared to that of pristine BiOI (similar to 29%). Thus, around three folds enhancement in the photocatalytic activity of BiOI-rGO (4wt%) catalyst was mainly attributed to ultrafast separation of electron-hole pairs and rapid transportation of carriers by rGO support. The superior photocatalytic activity demonstrated by this newly synthesized BiOI-rGO photocatalyst makes it's a potential candidate for environmental remediation process. (C) 2017 Elsevier B.V. All rights reserved.