• 文献标题:   3D structures of graphene oxide and graphene analogue MoS2 with polypyrrole for supercapacitor electrodes
  • 文献类型:   Article
  • 作  者:   PRASANKUMAR T, VIGNESHWARAN J, ABRAHAM S, JOSE SP
  • 作者关键词:  
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Madurai Kamaraj Univ
  • 被引频次:   6
  • DOI:   10.1016/j.matlet.2018.12.002
  • 出版年:   2019

▎ 摘  要

Transition metal dichalcogenides (TMDs) like Molybdenum disulfide (MoS2) are confessed as an effective energy storage materials due to their 2D structure analogues to graphene. Robust 3D architectures of graphene oxide-polypyrrole (GO-PPy) and molybdenum disulfide-polypyrrole (MoS2-PPy) were fabricated by facile, one pot chronoamperometry method to achieve scalable, conductive additive free and binder free supercapacitor electrodes. The electrodeposited GO-PPy and MoS2-PPy electrodes exhibit the specific capacitance of 271 F g(1) and 130 F g(1) respectively at a current density of 1 A g(1). The introduction of reduced graphene oxide (rGO) in PPy matrix offered high capacitance, whereas graphene analogue MoS2 improved the structural stability. Pronounced cycling stability (>2000 cycles) and note-worthy capacitive retentions were also displayed by these composites. MoS2-PPy and GO-PPy retain 82 and 64% of its initial capacitance respectively. These findings are backed up by the correlation of structure and electrochemical performance of GO-PPy and MoS2-PPy. (C) 2018 Elsevier B.V. All rights reserved.