• 文献标题:   Ultrathin MoS2 flakes embedded in nanoporous graphene films for a multi-functional electrode
  • 文献类型:   Article
  • 作  者:   KIM SW, HWANG J, HA SJ, LEE JE, YOON JC, JANG JH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1039/d0ta10397g
  • 出版年:   2021

▎ 摘  要

Molybdenum disulfide (MoS2) is considered a promising material in energy storage systems, and is thus drawing considerable attention. However, the relatively low conductivity of bulk MoS2 has been a threat for practical applications. This study developed a simple and scalable fabrication method of few-layer MoS2 sheets embedded in a nanoporous graphene film (NGF) as a high capacitance active material. Transfer of MoS2/NGF onto a flexible substrate followed by plotter cutting produced a highly efficient micro-supercapacitor with superior flexibility, mechanical stability, and great potential for applications in wearable electronics. Notably, MoS2/NGF-based mSC revealed a high volumetric capacitance of 55 F cm(-3) and 82.2% of capacitance retention after 20 000 cycles, which are superior to the reported data for solid-state micro-supercapacitors. With these performances, the flexible MoS2/NGF mSC exhibited an ultrahigh energy density of 7.64 mW h cm(-3) and power density of 9.96 W cm(-3) in a H3PO4 gel polymer electrolyte. The high volumetric capacitance and energy/power densities of MoS2/NGF as micro-supercapacitor electrodes are due to direct growth of ultra-thin MoS2 onto the interconnected 3D nanoporous graphene film with extended active sites and good conductivity. The MoS2/NGF mSC integrated on the skin efficiently powered a light emitting diode and strain sensors. This work suggests a meaningful way to realize film type MoS2 active materials in flexible micro-supercapacitors for wearable applications.