• 文献标题:   Electromagnetic shielding effectiveness of polycarbonate/graphene nanocomposite foams processed in 2-steps with supercritical carbon dioxide
  • 文献类型:   Article
  • 作  者:   GEDLER G, ANTUNES M, VELASCO JI, OZISIK R
  • 作者关键词:   porous material, polymeric composite, graphene, xray technique, electron microscopy
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Univ Politecn Catalunya BarcelonaTech UPC
  • 被引频次:   13
  • DOI:   10.1016/j.matlet.2015.07.070
  • 出版年:   2015

▎ 摘  要

The electromagnetic interference (EMI) shielding properties of polycarbonate/graphene composites foamed with supercritical carbon dioxide were investigated as a function of cellular morphology and graphene particle dispersion. The 2-step foaming method used was found to improve graphene dispersion and led to a different cellular structure compared to traditional 1-step foaming. Reflection was found to be the dominant EMI shielding mechanism and EMI shielding effectiveness was improved with large cell morphology that promoted isotropic/random orientation of graphene particles. A maximum EMI specific shielding effectiveness of similar to 78 dB cm(3)/g was achieved in foams, which was more than 70 times higher than that of the unfoamed polymer (1.1 dB cm(3)/g). The study shows that by controlling foaming process conditions and nanoparticle characteristics, it is possible to improve multiple properties while achieving lightweight materials suitable for various applications. (C) 2015 Elsevier B.V. All rights reserved.