• 文献标题:   Macro-Size Regenerated Cellulose Fibre Embedded with Graphene Oxide with Antibacterial Properties
  • 文献类型:   Article
  • 作  者:   MAZLAN NSN, SALLEH KM, KHAIRUNNISAATIQAH MK, HAFIZA AHA, MOSTAPHA M, ELLIS AV, ZAKARIA S
  • 作者关键词:   bioresource based product, naoh, urea, regenerated cellulose, solution mixing method, green product, production
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/polym15010230
  • 出版年:   2023

▎ 摘  要

Macro-size regenerated cellulose fibres (RCFs) with embedded graphene oxide (GO) were fabricated by dissolving cellulose in a pre-cooled sodium hydroxide (NaOH)/urea solution and regenerated in sulphuric acid (H2SO4) coagulant. Initially, GO was found to disperse well in the cellulose solution due to intercalation with the cellulose; however, this cellulose-GO intercalation was disturbed during the regeneration process, causing agglomeration of GO in the RCF mixture. Agglomerated GO was confirmed at a higher GO content under a Dino-Lite microscope. The crystallinity index (CrI) and thermal properties of the RCFs increased with increasing GO loadings, up to 2 wt.%, and reduced thereafter. Cellulose-GO intercalation was observed at lower GO concentrations, which enhanced the crystallinity and thermal properties of the RCF-GO composite. It was shown that the GO exhibited antibacterial properties in the RCF-GO composite, with the highest bacterial inhibition against E. coli and S. aureus.