• 文献标题:   Graphene wrapped 3,4,9,10-perylenetetracarboxylic dianhydride as a high-performance organic cathode for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   CUI DM, TIAN D, CHEN SS, YUAN LJ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   28
  • DOI:   10.1039/c6ta02880b
  • 出版年:   2016

▎ 摘  要

Graphene wrapped 3,4,9,10-perylenetetracarboxylic dianhydride (C24H8O6) composite materials have been successfully prepared through a facile heat-treatment process at different temperatures. Benefiting from the three-dimensional conductive network provided by the densely distributed graphene nanoplates, the composite material exhibits a high reversible capacity, an excellent cycling stability and a superior rate capability. When cycled against lithium in the potential range of 1.5 to 4.6 V, the composite material prepared at 400 degrees C exhibited an increasing discharge capacity at 100 mA g(-1) with a maximum value of 172 mA h g(-1) at the 180th cycle. In addition, the material is able to deliver reversible capacities of 152, 144, 134 and 110 mA h g(-1) at high current densities of 200, 300, 500 and 1000 mA g(-1), respectively, with 98% of the capacity retained after 200 cycles at 500 mA g(-1). The excellent electrochemical properties of the composite material make it a promising organic cathode material for large-scale lithium ion batteries.