• 文献标题:   Properties of polyaniline/graphene oxide (PANI/GO) composites: effect of GO loading
  • 文献类型:   Article, Early Access
  • 作  者:   AB MUTALIB TNABT, TAN SJ, FOO KL, LIEW YM, HEAH CY, ABDULLAH MMA
  • 作者关键词:   polyaniline, graphene oxide, pani, go composite, solution method
  • 出版物名称:   POLYMER BULLETIN
  • ISSN:   0170-0839 EI 1436-2449
  • 通讯作者地址:   Univ Malaysia Perlis UniMAP Level
  • 被引频次:   0
  • DOI:   10.1007/s00289-020-03334-w EA AUG 2020
  • 出版年:  

▎ 摘  要

Polyaniline/graphene oxide (PANI/GO) composites at different wt% of GO were prepared via solution method. PANI was mixed with the GO synthesized from the improved Hummer's method. The formation of GO was confirmed via Raman and C/O ratio. Based on the FT-IR, XRD and SEM results, it confirmed the presence of both PANI and GO characteristics at 10.9 degrees, 25.8 degrees and 27.8 degrees and interactions between PANI and GO particles in PANI/GO composites at different GO loading. SEM micrographs showed a folding and wrinkled surface of GO due to the defect upon oxidation process. This means that the weak pi-pi interactions or the agglomeration of GO have caused PANI unable to attach on the large conjugated basal planes of GO sheets. The defective domains made GO as an insulator as it contained distortions and oxygen-containing functional groups and their local decoration. Low-conductivity domain had conquered most of the GO region which later reduced the pathway of the current flow; therefore, conductivity is affected. The wrinkled structure also resulted in the low conductivity as it weakens the interfacial interaction between PANI and GO and thus disrupted the electron movement in the composites. Due to this, the electrical conductivity reached up to 1.83 x 10(-10) S/cm as the GO loading increased to 50 wt%.