• 文献标题:   A Direct Hybridization between Isocharged Nanosheets of Layered Metal Oxide and Graphene through a Surface-Modification Assembly Process
  • 文献类型:   Article
  • 作  者:   ADPAKPANG K, OH SM, JIN X, HWANG SJ
  • 作者关键词:   graphene, hybrid material, layered compound, lithiumion batterie, selfassembly
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Ewha Womans Univ
  • 被引频次:   6
  • DOI:   10.1002/chem.201403871
  • 出版年:   2014

▎ 摘  要

An efficient and universal method to directly hybridize isocharged nanosheets of layered metal oxide and reduced graphene oxide (rGO) is developed on the basis of the surface modification and an electrostatically driven assembly process. On the basis of this synthetic method, the CoO2-rGO nanocomposite can be synthesized with exfoliated CoO2 and rGO nanosheets, and transformed into CoO-CoO2-rGO nanocomposites with excellent electrode performance for lithium-ion batteries. Also, this surface-modification assembly route is successfully applied for the synthesis of another mesoporous TiO2-rGO nanocomposite. This result provides clear evidence for the usefulness of the present method as a universal way of hybridizing isocharged anionic nanosheets of inorganic solids and graphene.