• 文献标题:   Molybdenum carbide (Mo2C) and reduced graphene oxide (rGO) nano-composites as an efficient electrocatalyst for water splitting
  • 文献类型:   Article
  • 作  者:   LEE YH, BRAHMA S, HUANG PC, WANG SC, HUANG JL
  • 作者关键词:   composite material, microstructure, functional, hydrogen evolution reaction, transition metal carbide
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.matlet.2022.131934 EA MAR 2022
  • 出版年:   2022

▎ 摘  要

Hydrogen is one of the most promising renewable energy for production and storage to replace the fossil fuel and petroleum-based energy sources. Here, we prepared and used transition metal carbide (TMC) composite with the rGO (reduced graphene oxide) such as Mo2C-rGO to replace the platinum-based electrode. The synthesis of the composite involves a wet chemical method followed by a high-temperature carbonization treatment that led to the crystallization of the molybdenum precursor to molybdenum carbide and the graphene oxide to reduced graphene oxide (rGO). Microstructure analysis revealed the dispersion of Mo2C nanoparticles over rGO that achieved excellent HER (hydrogen evolution reaction) performance with an onset potential of -88 mV, better Tafel slope (67 mV dec(-1)) and outstanding stability. The HER performance was compared with composites prepared at different carbonization temperatures (750 degrees C-1050 degrees C) and with Mo2C-MOF (metal organic framework) and Mo2C-carbon black composite.