• 文献标题:   Ternary perovskite nickel titanate/reduced graphene oxide nano-composite with improved lithium storage properties
  • 文献类型:   Article
  • 作  者:   LI M, FAN XL, XIAO XZ, HUANG X, JIANG YQ, CHEN LX
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   9
  • DOI:   10.1039/c6ra09415e
  • 出版年:   2016

▎ 摘  要

As anode materials, TiO2 exhibits a suitable potential, fast kinetics and excellent cycling performance, while other transition metal oxides (such as NiO) deliver a much higher theoretical capacity with a moderate kinetics and limited cycling performance. Herein, a novel perovskite NiTiO3/reduced graphene oxide (RGO) composite with a particle size of 40-50 nm was first synthesized by solvothermal method and introduced as anode materials for lithium-ion batteries. The structure morphology and electrochemical performance of NiTiO3/RGO nanocomposite were investigated by X-ray diffraction (XRD), Raman spectroscopy measurements, scanning electron microscopy (SEM), transmission electron microscopy (TEM), galvanostatic charge-discharge tests, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) tests. The NiTiO3/RGO nanocomposite delivers a higher discharge capacity (1110.7 mA h g(-1)) and better cycling stability (65.3%), as well as improved rate capability over 50 cycles, compared with those of bare NiTiO3. The improved electrochemical properties of NiTiO3/RGO can be attributed to the good conductivity and large surface of RGO and the combination nanostructure of NiTiO3 and RGO.