• 文献标题:   Engineering ultrahigh-specific-capacity alpha-Fe2O3 nanoparticles and Ni(OH)(2)/Co0.85Se nanostructures separately anchored on N-doped graphene nanotubes toward alkaline rechargeable battery
  • 文献类型:   Article
  • 作  者:   MENG A, SHEN T, SONG GY, HUANG TQ, LIN YS, XUE HY, YUAN XC, ZHAO J, LI ZJ
  • 作者关键词:   alkaline rechargeable battery, ngnts@alphafe2o3 np, ngnts@ni oh 2 nas/co0.85se np, ultrahigh specific capacity, high energy density
  • 出版物名称:   MATERIALS CHARACTERIZATION
  • ISSN:   1044-5803 EI 1873-4189
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1016/j.matchar.2020.110375
  • 出版年:   2020

▎ 摘  要

In this paper, the N-doped graphene nanotubes (N-GNTs) are used as the scaffolds to grow alpha-Fe2O3 nanoparticles (NPs) and Ni(OH)(2) nanosheets arrays (NAs)/Co0.85Se nanoparticles (NPs) respectively, which are directly acted as hybrid negative and positive electrodes for alkaline rechargeable battery (ARB). The synergistic merits from the supporters and active materials enable the N-GNTs@ alpha-Fe2O3 NPs to deliver an ultrahigh specific capacity of 309 mAh g(-1) at 1 A g(-1), and good rate performance. By paring with the N-GNTs@ Ni(OH)(2) NAs/Co0.85Se NPs (268 mAh g(-1) at 1 A g(-1)), an ARB configuration is assembled. Contributed by the particular electrode architectures, the device displays a high energy density of 78.8 Wh kg(-1) at 2.47 kW kg(-1) and robust cycling life (91.3% retention of the initial specific capacity over 10,000 cycles). This strategy reported here opens up a new avenue to construct unique hybrid electrodes and maximizes their superiority, which leads to the ultrahigh capacity for the fabrication of next-generation energy storage devices.