• 文献标题:   Versatile chemical sensors using oligosaccharides on cleanable PDMS/graphene hybrids for monitoring environmentally hazardous substances
  • 文献类型:   Article
  • 作  者:   BAE J, HWANG Y, HA JH, KWON OS, JANG A, KIM HJ, AN J, LEE CS, PARK SH
  • 作者关键词:   chemical sensor, oligosaccharide, graphene, poly dimethylsiloxane, cyclodextrin, inclusion complex
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Dongduk Womens Univ
  • 被引频次:   0
  • DOI:   10.1016/j.apsusc.2019.145139
  • 出版年:   2020

▎ 摘  要

A versatile chemical sensor possessing a nontoxic sensing medium was produced for the detection of chemical environmental hazards. Poly(dimethylsiloxane) (PDMS)/graphene (GR) hybrids were employed as sensor substrates owing to their high electrical conductivity. The PDMS/GR hybrid substrates exhibited a significant change in electrical threshold above 1.2 wt% GR loading. Oligosaccharides, such as beta-cyclodextrin (beta-CD), were introduced and used as sensing media for the detection of potentially hazardous molecules. The successful introduction of the sensing medium was confirmed by a variety of instrumental analyses. The sensor signal generated by addition of target analyte originated from charge transport associated with the formation of beta-CD-analyte inclusion compounds, which were monitored by ultraviolet (UV) spectroscopy. The performance of this sensor system was examined using various concentrations of a model analyte, methyl paraben (MePRB), and yielded a limit of detection of approximately 10 nM.