• 文献标题:   Fluorescence chemical sensor based on water-soluble poly(p-phenylene ethynylene)-graphene oxide composite for Cu2+
  • 文献类型:   Article
  • 作  者:   ADACHI N, NAKAJIMA M, OKADA M, SUGENO M, NORIOKA T
  • 作者关键词:   watersoluble conjugated polymer, graphene oxide, chemical sensor, metal ion sensing, fluorescence change
  • 出版物名称:   POLYMERS FOR ADVANCED TECHNOLOGIES
  • ISSN:   1042-7147 EI 1099-1581
  • 通讯作者地址:   Tokyo Denki Univ
  • 被引频次:   2
  • DOI:   10.1002/pat.3633
  • 出版年:   2016

▎ 摘  要

A chemical sensor for metal ions was fabricated based on a water-soluble conjugated polymer-graphene oxide (GO) composite. Water-soluble poly(p-phenylene ethynylene) (PPE) with sulfonic acid side chain groups was used to prepare a very stable water-soluble PPE-GO composite with strong - interactions in water. The relationship between the optical properties and metal ion sensing capability of the PPE-GO composite in aqueous solution was investigated. Addition of metal ions enhanced the fluorescence intensity of the composite, and, in particular, the composite enabled the fluorescence detection of Cu2+ in aqueous solutions with high selectivity and sensitivity. Therefore, this conjugated polymer-GO composite sensor system was found to be an effective turn-on type chemical sensor for metal ions. Copyright (c) 2015 John Wiley & Sons, Ltd.