• 文献标题:   Graphene/Amorphous Carbon Restriction Structure for Stable and Long-Lifespan Antimony Anode in Potassium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   YANG X, ZHANG RY, XU SF, XU D, MA J, ZHANG ZY, YANG S
  • 作者关键词:   anode material, antimony, energy storage, potassiumion batterie, restriction structure
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Shenyang Aerosp Univ
  • 被引频次:   1
  • DOI:   10.1002/chem.201905311 EA APR 2020
  • 出版年:   2020

▎ 摘  要

Sb-based materials have attracted much attention owing to their ability to undergo a multi-electron alloy reaction with K+. However, there are still the serious problems of volume change and aggregation of particles, which lead to rapid capacity fading and a limited lifespan. In this work, a graphene/amorphous carbon restriction structure is proposed, in which the amorphous carbon layer on the surface of Sb nanoparticles can protect the particles from pulverization, and the graphene can buffer the volume change of the material. In addition, the conductive network formed by the dual carbon structure effectively improves the rate performance of the material. Thus, the material delivers a high capacity of 550 mA h g(-1) at 100 mA g(-1), a rate capability of 370 mA h g(-1) at 2000 mA g(-1), and a long lifespan of 350 cycles without significant capacity fading. The dual carbon strategy proposed offers a reference for the design of high-performance anode materials.