• 文献标题:   Geometry-dependent electrochemistry of graphene oxide family
  • 文献类型:   Article
  • 作  者:   SONG YP, FENG M, ZHAN HB
  • 作者关键词:   geometric structure, defect density, oxygen content, surface chemistry, surface microstructure
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Fuzhou Univ
  • 被引频次:   8
  • DOI:   10.1016/j.elecom.2015.04.003
  • 出版年:   2015

▎ 摘  要

The influence of graphene oxide geometry on electrochemical performance is of great interest, but there are few reports on this subject. Three different members of the graphene oxide family, graphene oxide nanosheets, graphene oxide nanoribbons, and graphene oxide quantum dots were comparatively investigated as electrode materials to systematically study the effect of geometric structure. The results showed that, as the geometric structure varies, the three graphene oxide materials possess different electrical conductivities, various defect densities and oxygen contents, as well as diverse electrode surface chemistry and microstructures, which combine together to result in the distinct electrochemical responses for the modified electrodes, depending on the redox system involved. This work broadens the method of studying the electrochemical performance of many other materials from the perspective of geometry. (C) 2015 Elsevier B.V. All rights reserved.