• 文献标题:   Pythium oligandrum-derived carbon/graphene oxide as sensitized substrate: large-scale preparation and enhancing photocatalytic hydrogen evolution
  • 文献类型:   Article, Early Access
  • 作  者:   ZHENG Q, MAO T, FANG YH, NIU YY, JI B, GONG XF, WANG PY, ZHAO J, YANG H, LUO D, HU L, ZHU Y, WANG ZY
  • 作者关键词:   poc, go nanohybrid material, separation of graphene oxide, dyesensitized photocatalytic h2 evolution, special configuration high conductivity
  • 出版物名称:   BIOMASS CONVERSION BIOREFINERY
  • ISSN:   2190-6815 EI 2190-6823
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s13399-023-03964-w EA FEB 2023
  • 出版年:   2023

▎ 摘  要

Pythium oligandrum-derived biomass-activated carbon/graphene oxide (POC/GO) nanohybrid material is prepared for the first time by direct carbonization using the two-dimensional graphene oxide (GO)-incorporated Pythiumoligandrum (PO). Note that the implanted GO is adsorbed and wrapped by the generated PO, which may be a feasible method to separate GO from aqueous systems. The obtained POC/GO exhibits special textural and high conductivity properties due to rapid electron transfer through the two-dimensional GO incorporated into carbonaceous network. Based on the functional POC/GO as a sensitizing substrate, the eosin Y dye-sensitized POC/GO@Pt photocatalysts show high-efficiency H-2 evolution activity, which is 1.3 and 2.1 times higher than GO@Pt and POC@Pt. As well as the apparent quantum efficiency of POC/GO@Pt can reach to 32.2% at 430 nm. The superior catalytic activities for H-2 evolution are attributed to the inner heat-treated GO which provided fast electron transport channels, while the outer POC with rich defect sites provided adsorption sites for the reactant H2O and co-catalyst Pt. Research ideas and design methods in this paper might provide a new way for preparing other biomass-based carbon materials and solar-driven high active photocatalyst.