• 文献标题:   Electropolymerization of the 3,4-Ethylenedioxythiophene on the Graphene Nanosheet in Ionic Liquid for Supercapacitors
  • 文献类型:   Article
  • 作  者:   JIN L, SUN D, ZHANG JR
  • 作者关键词:   graphene/pedot hybrid, electropolymerization, ionic liquid, supercapacitor
  • 出版物名称:   CHINESE JOURNAL OF INORGANIC CHEMISTRY
  • ISSN:   1001-4861
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   5
  • DOI:  
  • 出版年:   2012

▎ 摘  要

A novel high-performance supercapacitor electrode material based on graphene/Poly (3,4-ethylenedioxythiophene) (G/PEDOT) hybrid was synthesized via in situ electropolymerization of the 3,4-ethylenedioxythiophene (EDOT) monomer on the graphene nanosheet in ionic liquid for the first time. The morphology characterization of the G/PEDOT hybrid by AFM and SEM demonstrated that the grain-shape PEDOT particles with the average size of 80 nmx40 nmx2 nm were attached to the graphene sheet's surface tightly. The average specific capacitance of 181 F.g(-1) of the hybrid was obtained in the potential range from 0 to 0.8 V at 1.0 A.g(-1) by charge-discharge analysis and the hybrid showed good charge/discharge reversibility and electrochemical stability as supercapacitor electrode.