• 文献标题:   Fabrications and evaluations of hydrogen permeation on Al2O3/CeO2/graphene (ACG) composites membrane by Hot Press Sintering (HPS)
  • 文献类型:   Article
  • 作  者:   LEE NR, LEE SS, KIM KI, KIM WG, JU H, KIM DM, HONG TW
  • 作者关键词:   al2o3, ceo2, graphene, solgel, hydrogen permeation
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Korea Natl Univ Transportat
  • 被引频次:   5
  • DOI:   10.1016/j.ijhydene.2012.08.080
  • 出版年:   2013

▎ 摘  要

Ceramic membrane has high permeation rate of hydrogen and chemical stability. Al2O3 indicates stable at high temperature and a relatively large surface area. In addition, Al2O3 of porous is used as hydrogen separation membranes support, because of the high hydrogen permeability based on Knudsen diffusion mechanism. In this work, metal alkoxides as starting materials was used Aluminum isopropoxide powder. Then CeO2 as catalyst at the partial oxidation and Graphene Oxide as electrical conductivity are added, Al2O3 CeO2-Graphene oxide (ACG) composites are synthesized by sol gel process. ACG membrane was fabricated type of disk by Hot Press Sintering. A synthesized ACG composite material was characterized by EDS, SEM, TG/DTA, XRD, BET. The hydrogen permeation property of ACG membrane was measured by Sievert's type hydrogen permeation membrane equipment. The hydrogen permeability of ACG membranes was examined at RT-673 K under increasing pressure. Results, hydrogen permeability was obtained to 2.62 x 10(-7) mol/ms Pa-1/2 at 673 K under 0.3 MPa. (C) Copyright 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.