• 文献标题:   A novel porous reduced microcrystalline graphene oxide supported Fe3O4@C nanoparticle composite as anode material with excellent lithium storage performances
  • 文献类型:   Article
  • 作  者:   MA CL, SHI J, ZHAO Y, SONG NJ, WANG YX
  • 作者关键词:   microcrystalline graphene oxide, modified pressurized oxidation, lowcost, fe3o4@c/prmgo composite, high electrochemical performance
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:   Shanxi Univ
  • 被引频次:   16
  • DOI:   10.1016/j.cej.2017.05.180
  • 出版年:   2017

▎ 摘  要

The competitiveness of reduced graphene oxide (GO) based composite can be significantly improved when the raw material of GO become the low-cost microcrystalline graphite mine. Herein, we first successfully fabricate high-quality microcrystalline graphite GO (MGO) with small size < 1 mu m by a modified pressurized oxidation approach. Subsequently, Fe3O4@C/PrMGO composite is simply constructed by using porous reduced MGO (PrMGO) to support carbon coated Fe3O4 nanoparticles (Fe3O4@CNPs). The Fe3O4@C/PrMGO composite exhibits high reversible capacity and excellent cyclic stability that a high reversible capacity of 1216 mA h g(-1) is received after 392 cycles at 100 mA g(-1). Meanwhile, the composite possesses high rate retentions, superior structural and cycling stability, which are further revealed by rate test, SEM and EIS analyses. The significant advantages of Fe3O4@C/PrMGO composite (low cost, facile operation and high electrochemical performances) endow the composite to be practically promising anode material for next-generation LIBs. This research supplies a new strategy to fabricate low-cost and high performances MGO-based anode materials. (C) 2017 Elsevier B.V. All rights reserved.