• 文献标题:   Role of the synthesis route on the properties of hybrid LDH-graphene as basic catalysts
  • 文献类型:   Article
  • 作  者:   ALVAREZ MG, TICHIT D, MEDINA F, LLORCA J
  • 作者关键词:   graphene, layered double hydroxide, graphene oxide, hydrotalcite, heterogeneous catalyst, selfcondensation
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Inst Charles Gerhardt
  • 被引频次:   11
  • DOI:   10.1016/j.apsusc.2016.11.037
  • 出版年:   2017

▎ 摘  要

Layered double hydroxides (LDH or HT) or their derived mixed oxides present marked acid-base properties useful in catalysis, but they lead to agglomerate inducing a weak accessibility to the active sites. In this study we report the preparation and characterization of HT/Graphene (HT/rGO) nanocomposites as active and selective basic catalysts for the acetone condensation reaction. The graphene high specific surface area and structural compatibility with the HT allowed increasing the number and accessibility of the active sites and activity of this later. Two series of HT/rGO nanocomposites with 0.5