• 文献标题:   Formation of hexagonal boron nitride on graphene-covered copper surfaces
  • 文献类型:   Article
  • 作  者:   GOPALAN DP, MENDE PC, DE LA BARRERA SC, DHINGRA S, LI J, ZHANG KH, SIMONSON NA, ROBINSON JA, LU N, WANG QX, KIM MJ, D URSO B, FEENSTRA RM
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS RESEARCH
  • ISSN:   0884-2914 EI 2044-5326
  • 通讯作者地址:   Carnegie Mellon Univ
  • 被引频次:   6
  • DOI:   10.1557/jmr.2016.82
  • 出版年:   2016

▎ 摘  要

Graphene-covered copper surfaces have been exposed to borazine, (BH)(3)(NH)(3), with the resulting surfaces characterized by low-energy electron microscopy. Although the intent of the experiment was to form hexagonal boron nitride (h-BN) on top of the graphene, such layers were not obtained. Rather, in isolated surface areas, h-BN is found to form mu m-size islands that substitute for the graphene. Additionally, over nearly the entire surface, the properties of the layer that was originally graphene is observed to change in a manner that is consistent with the formation of a mixed h-BN/graphene alloy, i.e., h-BNC alloy. Furthermore, following the deposition of the borazine, a small fraction of the surface is found to consist of bare copper, indicating etching of the overlying graphene. The inability to form h-BN layers on top of graphene is discussed in terms of the catalytic behavior of the underlying copper surface and the decomposition of the borazine on top of the graphene.