• 文献标题:   CuCl2-doped graphene-based screen printing conductive inks
  • 文献类型:   Article
  • 作  者:   LIU LX, ZHANG XJ, MA H, SHEN ZG
  • 作者关键词:   graphene, cucl2, doping, conductive ink, uhf rfid antenna, flexible electrothermal film
  • 出版物名称:   SCIENCE CHINAMATERIALS
  • ISSN:   2095-8226 EI 2199-4501
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1007/s40843-021-1980-7 EA APR 2022
  • 出版年:   2022

▎ 摘  要

The preparation of graphene-based conductive inks and their application in the field of flexible electronics have been extensively studied. However, improving the conductivity of the printed patterns always induces the neglect of the rheological properties of the graphene-based conductive inks or the mechanical properties of the as-printed patterns. In this study, the p-type doping of graphene with CuCl2 as the dopant is realized through liquid phase reaction, and the doped graphene powders are used to prepare the graphene-based conductive inks with a conductivity of 3.13 x 10(4) S m(-1). Subsequently, to simplify the preparation of inks, CuCl2 is directly added into the graphene-based conductive inks, achieving the p-type doped graphene ink with the conductivity of 3.64 x 10(4) S m(-1). The read range of ultrahigh-frequency radio frequency identification antenna and the temperature of the flexible electrothermal film printed with the CuCl2-doped graphene-based conductive inks can reach 7.15 m and 200 degrees C, respectively when the equivalent isotropically radiated power is equal to 4 W and the input power density is 0.94 W cm(-2) . Moreover, good rheological properties of the conductive inks and high mechanical properties of the printed patterns are also obtained.