• 文献标题:   One-Pot Microwave-Assisted Synthesis of Graphene-Supported PtCoM (M = Mn, Ru, Mo) Catalysts for Low-Temperature Fuel Cells
  • 文献类型:   Article
  • 作  者:   NACYS A, KILMONIS T, KEPENIENE V, BALCIUNAITE A, STAGNIUNAITE R, UPSKUVIENE D, JABLONSKIENE J, VAICIUNIENE J, SKAPAS M, TAMASAUSKAITETAMASIUNAITE L, NORKUS E
  • 作者关键词:   graphene, transition metal, microwave irradiation, methanol, oxidation
  • 出版物名称:   CATALYSTS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/catal11121431
  • 出版年:   2021

▎ 摘  要

In this study, one-pot microwave-assisted synthesis was used to fabricate the graphene (GR)-supported PtCoM catalysts where M = Mn, Ru, and Mo. The catalysts with the molar ratios of metals Pt:Co:Mn, Pt:Co:Ru, and Pt:Co:Mo equal to 1:3:1, 1:2:2, and 7:2:1, respectively, were prepared. Catalysts were characterized using Transmission Electron Microscopy (TEM). The electrocatalytic activity of the GR-supported PtCoMn, PtCoRu, and PtCoMo catalysts was evaluated toward methanol oxidation in an alkaline medium employing cyclic voltammetry and chrono-techniques. The most efficient electrochemical characteristics demonstrated the PtCoMn/GR catalyst with a current density value of 144.5 mA cm(-2), which was up to 4.8 times higher than that at the PtCoRu(1:2:2)/GR, PtCoMo(7:2:1)/GR, and bare Pt/GR catalysts.