• 文献标题:   Chemical etching of InP assisted by graphene oxide
  • 文献类型:   Article
  • 作  者:   KUBOTA W, UTSUNOMIYA T, ICHII T, SUGIMURA H
  • 作者关键词:   graphene oxide, inp etching, catalyst
  • 出版物名称:   JAPANESE JOURNAL OF APPLIED PHYSICS
  • ISSN:   0021-4922 EI 1347-4065
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.35848/1347-4065/acc03a
  • 出版年:   2023

▎ 摘  要

Chemical etching of semiconductor surfaces assisted by various types of carbon-based materials is drawing much attention for the fabrication of those micro-nano structures. We herein demonstrated to apply graphene oxide (GO), a 2D nano-carbon material, as a catalyst for the InP etching reaction, and a possible mechanism of GO-assisted InP etching was suggested by combining XPS analyses. The solubility of the InP oxide layer towards the etching solution affected the rate-determining step of InP etching reaction. When the oxidant reduction reaction catalyzed by GO was the rate-determining step, the etching reaction under GO was enhanced. Furthermore, the etching behavior was different in utilizing different oxidants, which means that the catalytic activity of GO for the oxidant reduction also affects the etching behavior.