• 文献标题:   Enhanced electrochemical oxygen reduction reaction performance with Pt nanocluster catalysts supported on microporous graphene-like 3D carbon
  • 文献类型:   Article
  • 作  者:   KIM Y, LEE D, KWON Y, KIM TW, KIM K, KIM HJ
  • 作者关键词:   platinum nanocluster, graphene, zeolitetemplate, oxygen reduction reaction, fuel cell
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   KRICT
  • 被引频次:   4
  • DOI:   10.1016/j.jelechem.2019.02.035
  • 出版年:   2019

▎ 摘  要

Here we report an efficient catalyst design strategy to develop high performance Pt-based electrocatalysts for oxygen reduction reaction (ORR). Finely-dispersed Pt nanoclusters supported on microporous graphene-like 3D carbon (Pt/MGTC) having a Pt size of ca. 1.3 nm were synthesized by zeolite template-based carbon synthesis and subsequent Pt impregnation. The Pt/MGTC catalyst demonstrated about 2 times higher ORR activity than that of commercial Pt/C. In addition, the Pt/MGTC showed relatively stable ORR performance, maintaining an activity higher than that of Pt/C. This performance enhancement of electrocatalytic ORR on Pt/MGTC was attributed to the significant increase of Pt active sites and the efficient charge transport in Pt/MGTC.