• 文献标题:   Aqueous lithium and sodium ion capacitors with boron -doped graphene/ BDD/TiO 2 anode and boron -doped graphene/BDD cathode exhibiting AC line - filtering performance
  • 文献类型:   Article
  • 作  者:   YAN WK, LI MJ, LI HJ, LI CP, XU S, SU L, QIAN LR, YANG BH
  • 作者关键词:   graphene, diamond, titanium dioxide, boron doping, aqueous hybrid capacitor
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:   Tianjin Univ Technol
  • 被引频次:   1
  • DOI:   10.1016/j.cej.2020.124265
  • 出版年:   2020

▎ 摘  要

This paper reports our investigation of aqueous sodium and lithium ion capacitors (SIC and LIC, respectively) with a boron-doped graphene (BDG)/boron-doped diamond (BDD) cathode and BDG/nanocrystal BDD/TiO2 nanotube array anode. Vertically grown BDG nanosheets formed a porous three-dimensional morphology rich in charge storage sites with a short ion-diffusion distance and, high structural stability. In an aqueous NaCl solution, the potential windows are 0-1.1 V and-1.2-0 V for the cathode and anode, respectively, and their specific capacitances are 66.76 and 23.86 mF cm(-2) at a current density of 3 mA cm(-2), respectively. The devices exhibit high energy densities (SIC: 47.8 mu Wh cm(-2); LIC: 33.9 mu Wh cm(-2)) and high power densities (SIC: 77.7 mW cm(-2); LIC: 65.3 mW cm(-2)) at an operating voltage of 2.5 V. The SIC and LIC exhibited 100% coulombic efficiency over 10,000 cycles, with a capacitance retention of 99.5% and 97.8%, respectively, at a high current density of 90 mA cm(-2) over 2000 cycles. Moreover, the capacitors exhibit effective AC current filtering over a wide frequency range of 50-10,000 Hz. The coulombic efficiencies and long-term stabilities of these aqueous devices are better at high current densities, and large energy densities are retained at high power densities, which is advantageous for high-frequency filtering.