• 文献标题:   Enhancement in Performance of Sulfonated PES Cation-Exchange Membrane by Introducing Pristine and Sulfonated Graphene Oxide Nanosheets Synthesized through Hummers and Staudenmaier Methods
  • 文献类型:   Article
  • 作  者:   GERANI K, MORTAHEB HR, MOKHTARANI B
  • 作者关键词:   cationexchange membrane, hummers method, staudenmaier method, sulfonated graphene oxide, sulfonated polyether sulfone, transport propertie
  • 出版物名称:   POLYMERPLASTICS TECHNOLOGY ENGINEERING
  • ISSN:   0360-2559 EI 1525-6111
  • 通讯作者地址:   Chem Chem Engn Res Ctr Iran
  • 被引频次:   2
  • DOI:   10.1080/03602559.2016.1233260
  • 出版年:   2017

▎ 摘  要

Sulfonated polyether sulfone-based cation-exchange membranes are prepared by incorporating different amounts of graphene oxide and sulfonated graphene oxide nanosheets. The graphene oxide nanosheets are synthesized according to Staudenmaier and Hummer methods and functionalized using 3-mercaptopropyl trimethoxysilane. Transport properties of nanocomposite membranes including ion-exchange capacity, transport number, and conductivity as well as their thermal stabilities are enhanced by incorporating sulfonated graphene oxide rather than graphene oxide. Also, the enhancement is more significant for the nanocomposites having functionalized graphene oxide synthesized by Staudenmaier method than those by Hummers method due to higher density of active sites in the Staudenmier graphene oxides for functionalization.