• 文献标题:   Enhanced Electrode Performance of Fe2O3 Nanoparticle-Decorated Nanomesh Graphene As Anodes for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   ZHU X, SONG XY, MA XL, NING GQ
  • 作者关键词:   iron oxide, nanomesh graphene, composite, synergistic effect, catalytic activity, electrochemistry, lithium batterie
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   China Univ Petr
  • 被引频次:   67
  • DOI:   10.1021/am500323v
  • 出版年:   2014

▎ 摘  要

Nanostructured Fe2O3-nanomesh graphene (NMG) composites containing similar to 3 nm Fe2O3 nanoparticles (NPs) uniformly distributed in the nanopores of NMG are synthesized by an adsorption precipitation process. As anodes for Li ion batteries (LIBs), the 10%Fe2O3-NMG composite exhibits an upward trend in the capacity and delivers a reversible specific capacity of 1567 mA h g(-1) after 50 cycles at 150 mA g(-1), and 883 mA h g(-1) after 100 cycles at 1000 mA g(-1), much higher than the corresponding values for the NMG electrode. The significant capacity enhancement of the 10%Fe-NMG composite is attributed to the positive synergistic effect between NMG and Fe2O3 NPs due to the catalytic activity of Fe2O3 NPs for decomposition of the solid electrolyte interface film. Our results indicate that decoration of ultrasmall Fe2O3 NPs can significantly change the surface condition of graphene. This synthesis strategy is simple, effective, and broadly applicable for constructing other electrode materials for LIBs.