• 文献标题:   Facile Synthesis of Nitrogen-doped Graphene Derived from Graphene Oxide and Vitamin B3 as High-performance Sensor for Imidacloprid Determination
  • 文献类型:   Article
  • 作  者:   SI WM, LEI W, HAO QL, XIA XF, ZHANG H, LI J, LI QH, CONG RM
  • 作者关键词:   nitrogendoped graphene, pyridinen oxide, imidacloprid, sensor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Shandong Univ Technol
  • 被引频次:   7
  • DOI:   10.1016/j.electacta.2016.07.063
  • 出版年:   2016

▎ 摘  要

A stable and well-distributed nitrogen-doped graphene (NGE) is prepared by a simple and efficient hydrothermal method with a reducing-doping reagent of vitamin B3. Compared with NGE reduced by urea, vitamin B3 reduced NGE (NGE-N) showsuperior catalysis towards the electrochemical reduction of imidacloprid. The pyridine-N oxide induced in graphene sheets is considered enhancing the interaction between NGE-N and imidacloprid molecules. The NGE-N modified electrode is used in fast determination of imidacloprid with a low detection limit of 0.55 mu M. (C) 2016 Elsevier Ltd. All rights reserved.