• 文献标题:   Fluorescent graphene quantum dot nanoprobes for the sensitive and selective detection of mercury ions
  • 文献类型:   Article
  • 作  者:   WANG BJ, ZHUO SJ, CHEN LY, ZHANG YJ
  • 作者关键词:   graphene quantum dot, mercury ion, sensor, fluorescence analysi
  • 出版物名称:   SPECTROCHIMICA ACTA PART AMOLECULAR BIOMOLECULAR SPECTROSCOPY
  • ISSN:   1386-1425
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   71
  • DOI:   10.1016/j.saa.2014.04.129
  • 出版年:   2014

▎ 摘  要

Graphene quantum dots were prepared by ultrasonic route and served as a highly selective water-soluble probe for sensing of Hg2+. The fluorescence emission spectrum of graphene quantum dots was at about 430 nm. In the presence of Hg2+, the fluorescence of the quantum dots significantly quenched. And the fluorescence intensity gradually decreased with the increasing concentration of Hg2+. The change of fluorescence intensity is directly proportional to the concentration of Hg2+. Under optimum conditions, the linear range for the detection of Hg2+ was 8.0 x 10(-7) to 9 x 10(-6) M with a detection limit of 1.0 x 10(-7) M. In addition, the preliminary mechanism of fluorescence quenching was discussed in the paper. The constructed sensor with high sensitivity and selectivity, simple, rapid properties makes it valuable for further application. (C) 2014 Elsevier B.V. All rights reserved.