• 文献标题:   Mussel-Inspired Polydopamine-Functionalized Graphene as a Conductive Adhesion Promoter and Protective Layer for Silver Nanowire Transparent Electrodes
  • 文献类型:   Article
  • 作  者:   MIAO JL, LIU HH, LI W, ZHANG XX
  • 作者关键词:  
  • 出版物名称:   LANGMUIR
  • ISSN:   0743-7463
  • 通讯作者地址:   Tianjin Polytech Univ
  • 被引频次:   28
  • DOI:   10.1021/acs.langmuir.6b00796
  • 出版年:   2016

▎ 摘  要

For the scalable fabrication of transparent electrodes and optoelectronic devices, excellent adhesion between the conductive films and the substrates is essential. In this work, a novel mussel-inspired polydopamine-functionalized graphene/silver nanowire hybrid nanomaterial for transparent electrodes was fabricated in a facile manner. Graphene oxide (GO) was functionalized and reduced by polydopamine while remaining stable in water without precipitation. It is shown that the polydopamine-functionalized GO (PFGO) film adhered to the substrate much more easily and more uniformly than the GO film. The PFGO film had a sheet resistance of, similar to 3.46 X 10(8) Omega/sq and a transparency of 78.2%, with excellent thermal and chemical stability; these characteristics are appropriate for antistatic coatings. Further reduced PFGO (RPFGO) as a conductive adhesion promoter and protective layer for the Ag nanowire (AgNW) significantly enhanced the adhesion force between AgNW networks and the substrate. The RPFGO-AgNW electrode was found to have a sheet resistance of 63 Omega/sq and a transparency of 70.5%. Moreover, the long-term stability of the RPFGO-AgNW electrode was greatly enhanced via the effective protection of the AgNW by RPFGO. These solution-processed antistatic coatings and electrodes have tremendous potential in the applications of optoelectronic devices as a result of their low production cost and facile processing.