• 文献标题:   Low temperature direct growth of graphene patterns on flexible glass substrates catalysed by a sacrificial ultrathin Ni film
  • 文献类型:   Article
  • 作  者:   MARCHENA M, JANNER D, CHEN TL, FINAZZI V, PRUNERI V
  • 作者关键词:  
  • 出版物名称:   OPTICAL MATERIALS EXPRESS
  • ISSN:   2159-3930
  • 通讯作者地址:   Barcelona Inst Sci Technol
  • 被引频次:   15
  • DOI:   10.1364/OME.6.002487
  • 出版年:   2016

▎ 摘  要

Direct deposition of graphene on substrates would avoid costly, time consuming and defect inducing transfer techniques. In this paper we used ultrathin films of Ni, with thickness ranging from 5 to 50 nm, as a catalytic surface on glass to seed and promote chemical vapor deposition (CVD) of graphene. Different regimes and dynamics were studied for various parameters including temperature and reaction time. When a critical temperature (700 degrees C) was reached, Ni films retracted and holes formed that are open to the glass surface, where graphene deposited. After CVD, the residual Ni could be etched away and the glass substrate with graphene regained maximum transparency (>90%). The fact that we could achieve low growth temperatures indicates the potential of the technique to widen the range of substrate materials over which graphene can be directly deposited. We demonstrated this by depositing graphene patterns on ultrathin, 100 mu m thick, sheet of glass with low strain point (670 degrees C), particularly suitable for flexible electronic and optoelectronic devices. (C) 2016 Optical Society of America