• 文献标题:   Graphene Tunable Transparency to Tunneling Electrons: A Direct Tool To Measure the Local Coupling
  • 文献类型:   Article
  • 作  者:   GONZALEZHERRERO H, POU P, LOBOCHECA J, FERNANDEZTORRE D, CRAES F, MARTINEZGALERA AJ, UGEDA MM, CORSO M, ORTEGA JE, GOMEZRODRIGUEZ JM, PEREZ R, BRIHUEGA I
  • 作者关键词:   graphene, cu 111, electronic propertie, stm, dft, arpes
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Autonoma Madrid
  • 被引频次:   16
  • DOI:   10.1021/acsnano.6b00322
  • 出版年:   2016

▎ 摘  要

The local interaction between graphene and a host substrate strongly determines the actual properties of the graphene layer. Here we show that scanning tunneling microscopy (STM) can selectively help to visualize either the graphene layer or the substrate underneath, or even both at the same time, providing a comprehensive picture of this coupling with atomic precision and high energy resolution. We demonstrate this for graphene on Cu(111). Our spectroscopic data show that, in the vicinity of the Fermi level, graphene pi bands are well preserved presenting a small n-doping induced by Cu(111) surface state electrons. Such results are corroborated by Angle-Resolved Photoemission Spectra (ARPES) and Density Functional Theory with van der Waals (DFT + vdW) calculations. Graphene tunable transparency also allows the investigation of the interaction between the substrate and foreign species (such as atomic H or C vacancies) on the graphene layer. Our calculations explain graphene tunable transparency in terms of the rather different decay lengths of the graphene Dirac pi states and the metal surface state, suggesting that it should apply to a good number of graphene/substrate systems.