• 文献标题:   Highly oil-dispersed functionalized reduced graphene oxide nanosheets as lube oil friction modifier
  • 文献类型:   Article
  • 作  者:   ISMAIL NA, BAGHERI S
  • 作者关键词:   graphene, click chemistry, oildispersed, functionalization, additive, lube oil
  • 出版物名称:   MATERIALS SCIENCE ENGINEERING BADVANCED FUNCTIONAL SOLIDSTATE MATERIALS
  • ISSN:   0921-5107 EI 1873-4944
  • 通讯作者地址:   Univ Malaya
  • 被引频次:   11
  • DOI:   10.1016/j.mseb.2017.04.010
  • 出版年:   2017

▎ 摘  要

Unique mechanical properties of graphene make it an attractive candidate for many tribological applications such as additives for lube oil. However, within a few days of its preparation, graphene suffers from agglomeration and it can be prevented by introducing large structure molecules on the surface of GO. Covalent functionalization of GO is possible because there are multiple oxygen-containing functionalities on GO sheets. The conversion of highly water-soluble GO to high oil-soluble GO was also possible by covalent functionalization method. In this study, oil-soluble GO sheets were fabricated via functionalization of GO with organic moiety using CuAAC via Click chemistry. This study demonstrates that chemical strategy to provide graphene with organic moiety is important to obtain highly oil-dispersed GO sheets. This study revealed that the rGO(f) shows a significant effect in reducing friction and wear by 16% and 30% respectively and proved to be easily dispersed in oil. (C) 2017 Elsevier B.V. All rights reserved.