• 文献标题:   Study of the interfacial charge transfer in bismuth vanadate/reduce graphene oxide (BiVO4/rGO) composite and evaluation of its photocatalytic activity
  • 文献类型:   Article
  • 作  者:   SAJID MM, SHAD NA, JAVED Y, KHAN SB, ZHANG ZJ, AMIN N
  • 作者关键词:   bivo4, rgo, photocatalysi, methylene blue, photoluminescence, water purification
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Govt Coll Univ
  • 被引频次:   5
  • DOI:   10.1007/s11164-019-04029-2 EA OCT 2019
  • 出版年:   2020

▎ 摘  要

We prepared unique BiVO4/reduce graphene oxide (BiVO4/rGO) nanocomposite with enhanced photocatalytic ability by hydrothermal method applying Bi(NO3)(3)center dot 5H(2)O, NH4VO3 and graphene oxide as precursors. The physical and chemical attributes were characterized by various analytical techniques; X-ray diffractometer, scanning electron microscope, energy dispersive spectrum analysis, Fourier-transform infrared spectroscopy, X-ray photon spectroscopy, surface area Brunauer-Emmett-Teller analyzer and photoluminescence. Methylene blue was used as a pollutant and degraded under visible light irradiation; the photocatalytic activity of BiVO4/rGO nanocomposite was observed 29% higher than the pure BiVO4 catalyst. The graphene enhanced the surface adsorption property and increased the charge separation efficiency of photo-created charge carriers; moreover, the photoactivity of BiVO4 increased considerably. The mechanism for the BiVO4/rGO nanocomposite was purposed and discussed critically, which suggests that graphene acts as electron trapper and tuning the bandgap energy led to superior photocatalytic activity.