• 文献标题:   Non-enzymatic amperometric hydrogen peroxide sensor using a glassy carbon electrode modified with gold nanoparticles deposited on CVD-grown graphene
  • 文献类型:   Article
  • 作  者:   YUAN YW, ZHENG YQ, LIU JL, WANG H, HOU SF
  • 作者关键词:   chemical vapor deposition, sputtering, electrochemical sensing, synergistic effect, amperometry, poly methylmethacrylate
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Shandong Univ
  • 被引频次:   3
  • DOI:   10.1007/s00604-017-2499-2
  • 出版年:   2017

▎ 摘  要

A glassy carbon electrode (GCE) was modified with gold nanoparticles (AuNPs) coated on monolayer graphene (AuNP/MG) by direct in situ sputtering of AuNPs on CVD-generated graphene. This process avoids complicated polymer transfer and polymer cleaning processes and affords AuNPs with a clean surface. The monolayer graphene is ductile and well dispersed. The clean surface of the AuNPs renders this sensor superior to GCEs modified with AuNPs on reduced graphene oxide in terms of the amperometric nonenzymatic determination of hydrogen peroxide. The detection limit is 10 nM (S/N = 3) at 0.55 V (vs. SCE), which is lower than that for similar methods, and the response time is as short as 2 s. Another attractive feature of the sensor is its feasibility for large-scale production via CVD and sputtering.