• 文献标题:   Rapid preparation of CuO composite graphene for portable electrochemical sensing of sulfites based on laser etching technique
  • 文献类型:   Article
  • 作  者:   LI P, PAN P, LIU J, YANG XP, YANG ZC, ZHOU J, LIU GY, SHEN HD, ZHANG XD
  • 作者关键词:   sulfite detection, electrochemical sensor, onestep laserinduce, screen printed electrode, high sensitivity
  • 出版物名称:   MICROCHEMICAL JOURNAL
  • ISSN:   0026-265X EI 1095-9149
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.microc.2022.108096 EA NOV 2022
  • 出版年:   2022

▎ 摘  要

Sulfite (SO2- 3 ) is mostly used as a preservative in food products, and excessive human intake can lead to cardiac and cerebral discomfort and other adverse effects. Considering the high cost of existing SO2-3 detection methods and the complexity of sample handling, this study is based on laser-induced graphene technology and the simultaneous preparation of multisite copper oxide (CuO) nanoparticles and their attachment to the graphene surface, which can help to fully contact with SO2-3 , so as to develop a highly sensitive and consistent screen -printed electrode as an electrochemical sensor (CuO/rGO/SPE). A portable electrochemical workstation and a specially designed snap-in interface are then used for portable detection of SO2-3. The structure and composition of CuO were determined by scanning electron microscopy (SEM) and X-ray diffraction (XRD), etc. The elec-trochemical performance of the CuO/rGO/SPE sensor was evaluated by cyclic voltammetry (CV) and electro-chemical impedance spectroscopy (EIS). The linear response range of the electrode was 1-300 mu M, the electrode sensitivity was 122.3 mu Acm- 2mM-1, and the detection limit was 0.2425 mu M. Therefore, the CuO/rGO/SPE electrode has remarkable selectivity, stability, and reliability.