• 文献标题:   Quality assessment of graphene: Continuity, uniformity, and accuracy of mobility measurements
  • 文献类型:   Article
  • 作  者:   MACKENZIE DMA, BURON JD, WHELAN PR, CARIDAD JM, BJERGFELT M, LUO B, SHIVAYOGIMATH A, SMITSHUYSEN AL, THOMSEN JD, BOOTH TJ, GAMMELGAARD L, ZULTAK J, JESSEN BS, BOGGILD P, PETERSEN DH
  • 作者关键词:   chemical vapordeposited cvd graphene, doping inhomogeneity, electrical measurement, van der pauw, hbnencapsulated graphene, finite element simulation, raman mapping
  • 出版物名称:   NANO RESEARCH
  • ISSN:   1998-0124 EI 1998-0000
  • 通讯作者地址:   Tech Univ Denmark
  • 被引频次:   14
  • DOI:   10.1007/s12274-017-1570-y
  • 出版年:   2017

▎ 摘  要

With the increasing availability of large-area graphene, the ability to rapidly and accurately assess the quality of the electrical properties has become critically important. For practical applications, spatial variability in carrier density and carrier mobility must be controlled and minimized. We present a simple framework for assessing the quality and homogeneity of large-area graphene devices. The field effect in both exfoliated graphene devices encapsulated in hexagonal boron nitride and chemical vapor-deposited (CVD) devices was measured in dual current-voltage configurations and used to derive a single, gate-dependent effective shape factor, beta, for each device. beta is a sensitive indicator of spatial homogeneity that can be obtained from samples of arbitrary shape. All 50 devices investigated in this study show a variation (up to tenfold) in beta as a function of the gate bias. Finite element simulations suggest that spatial doping inhomogeneity, rather than mobility inhomogeneity, is the primary cause of the gate dependence of beta, and that measurable variations of beta can be caused by doping variations as small as 10(10) cm(-2). Our results suggest that local variations in the position of the Dirac point alter the current flow and thus the effective sample shape as a function of the gate bias. We also found that such variations lead to systematic errors in carrier mobility calculations, which can be revealed by inspecting the corresponding beta factor.