• 文献标题:   Making few-layer graphene photoluminescent by UV ozonation
  • 文献类型:   Article
  • 作  者:   ZHANG ZY, TAO HH, LI H, DING GQ, NI ZH, CHEN XF
  • 作者关键词:  
  • 出版物名称:   OPTICAL MATERIALS EXPRESS
  • ISSN:   2159-3930
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   3
  • DOI:   10.1364/OME.6.003527
  • 出版年:   2016

▎ 摘  要

Ultraviolet (UV) ozonation is employed for making graphene photoluminescent. We find that photoluminescence (PL) varies with the ozonation temperature. For room-temperature ozonized few-layer graphene (FLG), PL is localized at the edges and in the suspended areas of FLG. At an ozonation temperature of 120 degrees C, PL localized at the edges of FLG disappears, and the surface of trilayer graphene becomes luminescent. These graphene flakes are topographically and chemically characterized to understand the origin of PL. We propose that sp(2) clusters play a key role in making graphene photoluminescent, and that intact carbon layers and charged impurities at the surface of silicon oxide substrate may quench PL. (C) 2016 Optical Society of America