▎ 摘 要
A novel voltammetric sensor was designed and used for the determination ofl-tyrosine (l-Tyr) by surface modification of a glassy carbon electrode with reduced graphene oxide-hemin-Ag (rGO-H-Ag) nanocomposites. The nanocomposites were synthesized by a facile one-pot hydrothermal method and characterized by means of transmission electron microscopy and Raman spectroscopy. The determination ofl-Tyr was investigated by cyclic voltammetry and further quantified using differential pulse voltammetry. The results revealed a significant enhanced electrochemical oxidation effect forl-Tyr at the nanocomposites modified electrode. Two linear ranges from 0.1 to 100 mu M and 100 to 1000 mu M as well as a low detection limit of 30 nM (S/N = 3) were obtained. In addition, the sensor also demonstrated good selectivity, reproducibility and stability.